The title complex, [Cu(2)(C(13)H(11)F(2)N(6)O)(2)](ClO(4))(2), which was hydro-thermally synthesized, contains a binuclear copper cluster (2 symmetry) with a Cu(2)O(2) rhombus [Cu-O = 1.927â (2)â à ] formed by donation of two O atoms from two chelate rings. The tridentate function of each ligand is completed by two N atoms coordinated to the two Cu(II) atoms [Cu-N = 1.933â (2)â à ]. The separation distance of two Cu(II) atoms in a cluster is 2.988â (1)â à . The dihedral angle between the six-membered chelate rings is 2.13â (9)°. The perchlorate counter-anion is disordered over two sites in a 0.58â (10):0.42â (10) ratio.
Bis[μ-2-(2,4-difluoro-phen-yl)-1,3-bis-(1H-1,2,4-triazol-1-yl)propan-2-olato]dicopper(II) bis-(perchlorate).
双[α-2-(2,4-二氟苯基)-1,3-双-(1H-1,2,4-三唑-1-基)丙-2-醇]二铜(II)双-(高氯酸盐)。
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| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Mar 10; 66(Pt 4):m391 |
| doi: | 10.1107/S1600536810008512 | ||
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