In the title complex, [Cu(C(5)H(5)N(2)O(2))(C(14)H(18)N(3)O)(H(2)O)]·1.33H(2)O, the Cu(II) ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxy-imidazol-1-ide ligand and by one O atom and one N atom from a 5-methyl-1H-pyrazole-3-carboxyl-ate ligand. The apical position is occupied by a water mol-ecule. In the crystal structure, O-Hâ¯O, O-Hâ¯N and N-Hâ¯O hydrogen bonds lead to a three-dimensional supra-molecular network.
Aqua-[2-(5-ethyl-2-pyridyl-κN)-4-iso-propyl-4-methyl-5-oxo-4,5-dihydroxy-imidazol-1-ido-κN](5-methyl-1H-pyrazole-3-carboxyl-ato-κN,O)copper(II) 1.33-hydrate.
Aqua-[2-(5-乙基-2-吡啶基-κN)-4-异丙基-4-甲基-5-氧代-4,5-二羟基-咪唑-1-ido-κN](5-甲基-1H-吡唑-3-羧酸根-κN,O)铜(II) 1.33-水合物。
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| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Dec 19; 66(Pt 1):m79 |
| doi: | 10.1107/S1600536809053768 | ||
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