In the title complex, [Ni(2)(C(13)H(11)F(2)N(6)O)(2)(C(2)H(3)O(2))(2)]·0.5CH(3)OH, there are two half-molecules in the asymmetric unit. The two centrosymmetrically related Ni(II) atoms, each attached to an acetate ligand, are linked by two fluconazole ligands. Each Ni(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms of the triazole groups and two bridging O atoms from two different fluconazole ligands and two O atoms from a chelating acetate ligand. In the crystal structure, the half-occupied methanol solvent mol-ecule is linked to a triazole group via an O-Hâ¯N hydrogen bond.
Bis[μ-2-(2,4-difluoro-phen-yl)-1,3-bis-(1,2,4-triazol-1-yl)propan-2-olato-κN,O:O,N]bis-[(acetato-κO,O')nickel(II)] methanol hemisolvate.
双[μ-2-(2,4-二氟-苯-基)-1,3-双-(1,2,4-三唑-1-基)丙-2-olato-μN,O:O,N]双-[(乙酰基-μO,O')镍(II)]甲醇半溶剂化物。
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| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2009 | 起止号: | 2009 Dec 19; 66(Pt 1):m75-6 |
| doi: | 10.1107/S160053680905377X | ||
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