In the title compound, C(14)H(8)Br(2)FN(3)O(2), the 4-fluoro-phenyl ring and the nitro-substituted phenyl ring form a dihedral angle of 64.37â (10)°. Mol-ecules in the crystal are connected by C-Hâ¯O and C-Hâ¯F hydrogen bonds into layers parallel to (011). The crystal packing is consolidated by C-Brâ¯Ï and C-Fâ¯Ï inter-actions, as well as by Ï-Ï stacking inter-actions. According to a Hirshfeld surface analysis of the crystal structure, the most significant contributions to the crystal packing are from Oâ¯H/Hâ¯O (15.0%), Hâ¯H (14.3%), Brâ¯H/Hâ¯Br (14.2%), Câ¯H/Hâ¯C (10.1%), Fâ¯H/Hâ¯F (7.9%), Brâ¯Br (7.2%) and Brâ¯C/Câ¯Br (5.8%) contacts.
Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-di-bromo-1-(4-nitro-phen-yl)ethen-yl]-2-(4-fluoro-phen-yl)diazene.
(E)-1-[2,2-二溴-1-(4-硝基苯基)乙烯基]-2-(4-氟苯基)二氮烯的晶体结构和Hirshfeld表面分析。
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| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2022 | 起止号: | 2022 Apr 28; 78(Pt 5):530-535 |
| doi: | 10.1107/S2056989022004388 | ||
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