Selective Production of Bio-Based Linear Alpha-Olefin from Wasted Fatty Alcohol on Al2O3 for Bio-Based Chemicals

在 Al2O3 上从废弃脂肪醇中选择性生产生物基线性 α-烯烃,用于生物基化学品

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作者:Hye-Jin Lee, Il-Ho Choi, Seung-Wook Kim, Kyung-Ran Hwang

Results

93% conversion, 62% selectivity of 1-octadecene (C18H36), and 89% LAO purity. This was attributed to the increased Al/O ratio and atomic concentration of surface O in alumina, which were important factors in the catalytic dehydration of 1-octadecanol through the synergistic catalysis of acid-base pairs. The produced bio-based LAO can be key intermediates for synthesis of oxo alcohols and poly-alpha-olefins, as alternatives to petroleum-based LAO to achieve carbon neutrality in chemical industry.

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