The Effect of Acceptor Structure on Emission Color Tuning in Organic Semiconductors with D-π-A-π-D Structures

受体结构对D-π-A-π-D结构有机半导体发光颜色调控的影响

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作者:Przemyslaw Ledwon, Gabriela Wiosna-Salyga, Marian Chapran, Radoslaw Motyka

Abstract

A series of novel donor-acceptor D-π-A-π-D compounds were synthesized and characterized in order to determine the influence of different acceptor units on their properties. The introduction of acceptor moieties had a direct impact on the HOMO and LUMO energy levels. Fluorescence spectra of compounds can be changed by the choice of an appropriate acceptor and were shifted from the green to the near-infrared part of spectra. Due to observed concentration induced emission quenching, the green exciplex type host was used to evaluate the potential of synthesized molecules as emitters in organic light emitting diodes (OLEDs).

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