Abstract
The crystal structure of title salt, C14H36N4 4+·2ClO4 -·2Cl-, has been determined using synchrotron radiation at 220 K. The structure determination reveals that protonation has occurred at all four amine N atoms. The asymmetric unit contains one half-cation (completed by crystallographic inversion symmetry), one perchlorate anion and one chloride anion. A distortion of the perchlorate anion is due to its involvement in hydrogen-bonding inter-actions with the cations. The crystal structure is consolidated by inter-molecular hydrogen bonds involving the 1,4,8,11-tetra-methyl-1,4,8,11-tetra-azonia-cyclo-tetra-decane N-H and C-H groups as donor groups, and the O atoms of the perchlorate and chloride anion as acceptor groups, giving rise to a three-dimensional network.