Structural and Superconducting Properties of Thermal Treatment-Synthesised Bulk YBa₂Cu₃O7-δ Superconductor: Effect of Addition of SnO₂ Nanoparticles

热处理合成块状 YBa₂Cu₃O7-δ 超导体的结构和超导特性:添加 SnO₂ 纳米粒子的影响

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作者:Nur Nabilah Mohd Yusuf, Mohd Mustafa Awang Kechik, Hussein Baqiah, Chen Soo Kien, Lim Kean Pah, Abdul Halim Shaari, Wan Nur Wathiq Wan Jusoh, Safia Izzati Abd Sukor, Mustafa Mousa Dihom, Zainal Abidin Talib, Roslan Abd-Shukor1

Abstract

YBa&sub2;Cu&sub3;O7-δ (Y-123) bulk superconductors with the addition of (0.0, 0.2, 0.4, 0.6, 0.8, and 1.0 wt.%) SnO&sub2; nanoparticles were synthesised via a thermal treatment method. The influence of SnO&sub2; addition on the superconducting properties by means of critical temperature, Tc, AC susceptibility, phase formation and microstructures, including its elemental composition analysis, were studied. Sharp superconducting transition, ∆Tc, and diamagnetic transition were obtained for all SnO&sub2;-added samples. It was observed that sample x = 0.4 with a Y-123 phase percentage of 95.8% gives the highest Tc, smallest ∆Tc, and the sharpest diamagnetic transition in the normalised susceptibility curves. The microstructure also showed an excess of Sn precipitates on the sample's surface at x = 0.8 and above. As such, the best superconducting properties were observed at x = 0.4 SnO&sub2; addition inside the Y-123 host sample.

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