The title compound, [Pb(2)(C(2)O(4))(NO(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized hydro-thermally. The binuclear complex mol-ecule is centrosymmetric, the inversion centre being located at the mid-point of the oxalate C-C bond. The Pb(II) ion is hepta-coordinated by the O atom of one water mol-ecule, two oxalate O atoms, two nitrate O atoms and two 2,2'-bipyridine N atoms, forming an irregular coordination environemnt. Inter-molecular O-Hâ¯O hydrogen bonds between water mol-ecules and oxalate and nitrate ions result in the formation of layers parallel to (010). Ï-Ï inter-actions between pyridine rings in adjacent layers, with centroid-centroid distances of 3.584â (2)â à , stabilize the structural set-up.
μ-Oxalato-κ(4)O(1),O(2):O(1'),O(2')-bis-[aqua-(2,2'-bipyridine-κN)(nitrato-κ(2)O,O')lead(II)].
μ-草酸根-μ(4)O(1),O(2):O(1'),O(2')-双-[水-(2,2'-联吡啶-μN)(硝基-μ(2)O,O')铅(II)]。
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| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Oct 1; 68(Pt 10):m1310 |
| doi: | 10.1107/S1600536812040196 | ||
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