In the title compound, [NiCl(C(10)H(7)N(3)S)(2)(H(2)O)]NO(3), the Ni(II) ion is coordinated by four N atoms from two chelating 2-(1,3-thia-zol-4-yl)-1H-benzimidazole ligands, one Cl atom and one water mol-ecule in a distorted octa-hedral geometry. In the crystal, O-Hâ¯O, N-Hâ¯O and N-Hâ¯Cl hydrogen bonds link the complex cations and nitrate anions into a three-dimensional network. Ï-Ï inter-actions between the thia-zole and imidazole rings and between the thia-zole and benzene rings are observed [centroid-centroid distances = 3.592â (3) and 3.735â (3)â à ].
Aquachloridobis[2-(1,3-thia-zol-4-yl-κN)-1H-benzimidazole-κN(3)]nickel(II) nitrate.
水氯双[2-(1,3-硫杂-唑-4-基-γN)-1H-苯并咪唑-γN(3)]硝酸镍。
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| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Aug 1; 68(Pt 8):m1029 |
| doi: | 10.1107/S1600536812029728 | ||
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